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5-2.2.1 Chemical Reaction. Chemically reacting ows are those in which the chemical composition, properties, and temperature change as the result of a simple or complex chain of reactions in the uid. Depending on the implementation, reacting ows can require the solution of multiple conservation equations for species, some of which describe reactants, and others of which describe products. To balance the mass transfer from one species to another, reaction rates are used in each species conservation equation, and have as factors the molecular weights, concentrations, and stoichiometries for that species in all reactions. Consider, for example, the single-step rst-order reaction A + B R, for which the reaction rate is given by

ef ciently through a single circulation loop from axial ow impellers, whereas dispersion of gas bubbles is better obtained with dual circulation loops using radial ow disk impellers The ow patterns with a given impeller are altered by parameters such as impeller diameter, liquid viscosity, and use of multiple impellers For example, the ow pattern with a PBT becomes closer to radial as the impeller diameter is increased (Figure 6-20d ) or liquid viscosity is increased (Figure 6-20e) Multiple impellers are used when liquid depth/tank diameter ratio is higher than 10 In that case, more circulation loops are formed (eg, two loops with PBT; Figure 6-20f ) Radial ow impellers give two circulation loops with each impeller For suspension of sinking solids, it is important to provide liquid velocities directed to the tank oor for an effective sweeping action Hydrofoils perform well in this duty.

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However, if the solids have any tendency to be sticky and cling to the blades, the effectiveness of a hydrofoil can be reduced This can reduce its versatility as a multipurpose impeller In addition to suspending solids off the tank bottom, a process may require homogeneous suspension throughout the bulk An additional axial ow impeller, perhaps an up-pumping one, may be needed at a higher level for this purpose Radial ow impellers can be designed to suspend solids, especially if placed on the bottom of the tank, but are less ef cient and provide relatively poor solids homogeneity in the bulk When using axial ow impellers, the mixer rotation can be reversed to create up-pumping action This pumping mode can be effective for some systems, such as entrainment of oating solids and gas dispersion.

Table 7-2: Table Option Meanings Based on Data Source TABLES Tables are shown as Tables Used in conjunction with System Tables to show worksheet tabs and data User tables are shown as Tables Database views are shown as Views Database views are shown as Views Database system tables are shown as System Tables Database system Tables are shown as System Tables Public and private synonyms are shown as Synonyms SQL 2005 synonyms are not supported Used in conjunction with Tables to show worksheet tabs and data Database schemas are shown as Owners Database owners are shown as Owners (usually dbo) Queries are shown as Views Hidden system tables are shown as System Tables VIEWS SYSTEM TABLES SYNONYMS OWNER

The up-pumping ow provides an effective mechanism for incorporating lighter solids on the liquid surface near the wall This avoids the need for creating a vortex, which can cause air entrainment and mechanical vibrations (see 10) For gas dispersion, the up-pumping impeller is generally used at the bottom along with a down-pumping impeller at the top Such a con guration can provide good gas-holding capacity and prevent mechanical vibrations caused by opposite ows resulting from a down-pumping impeller at the bottom Up-pumping applications are relatively new and require careful testing and study before use (see 11) For effective blending of liquids in large tanks using side-entering propeller mixers, it is important to create the ow patterns shown in Figure 6-21 This is achieved by positioning the horizontal mixer 10 degrees to the left of tank centerline, assuming that the propeller rotates clockwise looking from the motor side.

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If the mixer is positioned along the tank centerline, the jet ow can cause vortexing on the surface This vortexing can reduce blending ef ciency and possibly entrain air into the liquid product Variations in ow patterns for axial ow impellers can be generated to advantage by changing the impeller position or by baf ing For example, axial ow impellers provide radial ows when placed near the tank bottom For submergence of oating solids, the tank is often unbaf ed in the top half to create a controlled vortex useful for pulling down solids The same method can also be used for surface inducement of gas from vapor space (Oldshue, 1983) and.

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